| # | Flag | Country | Population in the largest city (% of urban population)Population in the largest city (% of urban population) | Year |
|---|---|---|---|---|
| 1 | Macao | 100% | 2018 | |
| 2 | Singapore | 100% | 2018 | |
| 3 | Hong Kong | 99.7% | 2018 | |
| 4 | Puerto Rico | 82.09% | 2018 | |
| 5 | Djibouti | 75.29% | 2018 | |
| 6 | Paraguay | 75.22% | 2018 | |
| 7 | Trinidad and Tobago | 73.65% | 2018 | |
| 8 | Kuwait | 72.25% | 2018 | |
| 9 | Mongolia | 70.07% | 2018 | |
| 10 | Guinea-Bissau | 68.71% | 2018 | |
| 11 | Republic of the Congo | 63.54% | 2018 | |
| 12 | Panama | 63.06% | 2018 | |
| 13 | Burundi | 61.73% | 2018 | |
| 14 | Eritrea | 60.41% | 2011 | |
| 15 | Armenia | 57.96% | 2018 | |
| 16 | Liberia | 57.54% | 2018 | |
| 17 | Togo | 53.06% | 2018 | |
| 18 | Uruguay | 52.82% | 2018 | |
| 19 | Cambodia | 51.37% | 2018 | |
| 20 | Mauritania | 51% | 2018 | |
| 21 | Rwanda | 49.96% | 2018 | |
| 22 | Georgia | 49.25% | 2018 | |
| 23 | Israel | 48.85% | 2018 | |
| 24 | Latvia | 48.53% | 2018 | |
| 25 | Republic of Macedonia | 48.39% | 2018 | |
| 26 | Estonia | 48.03% | 2018 | |
| 27 | Egypt | 47.76% | 2018 | |
| 28 | Central African Republic | 44.09% | 2018 | |
| 29 | Portugal | 43.66% | 2018 | |
| 30 | Burkina Faso | 43.65% | 2018 | |
| 31 | Kyrgyzstan | 43.4% | 2018 | |
| 32 | Gabon | 42.95% | 2018 | |
| 33 | Haiti | 42.88% | 2018 | |
| 34 | Afghanistan | 42.33% | 2018 | |
| 35 | Peru | 41.69% | 2018 | |
| 36 | Azerbaijan | 41.29% | 2018 | |
| 37 | Guinea | 41.08% | 2018 | |
| 38 | Chile | 40.73% | 2018 | |
| 39 | Bahrain | 40.29% | 2018 | |
| 40 | Senegal | 39.81% | 2018 | |
| 41 | Equatorial Guinea | 39.81% | 2018 | |
| 42 | Lebanon | 39.31% | 2018 | |
| 43 | Republic of Ireland | 39.19% | 2018 | |
| 44 | Ivory Coast | 38.66% | 2018 | |
| 45 | Angola | 38.52% | 2018 | |
| 46 | Sudan | 38.22% | 2018 | |
| 47 | Greece | 37.21% | 2018 | |
| 48 | Chad | 37.06% | 2018 | |
| 49 | Austria | 36.85% | 2018 | |
| 50 | New Zealand | 36.82% | 2018 | |
| 51 | Dominican Republic | 36.82% | 2018 | |
| 52 | Argentina | 36.61% | 2018 | |
| 53 | Jamaica | 36.05% | 2018 | |
| 54 | Serbia | 35.48% | 2018 | |
| 55 | Oman | 35.43% | 2018 | |
| 56 | Tajikistan | 35.34% | 2018 | |
| 57 | Sierra Leone | 35.31% | 2018 | |
| 58 | Democratic Republic Of Congo | 35.24% | 2018 | |
| 59 | Costa Rica | 34.23% | 2018 | |
| 60 | Moldova | 33.72% | 2018 | |
| 61 | Malawi | 33.51% | 2018 | |
| 62 | United Arab Emirates | 33.43% | 2018 | |
| 63 | Zambia | 33.42% | 2018 | |
| 64 | Bangladesh | 33.12% | 2018 | |
| 65 | Namibia | 33% | 2018 | |
| 66 | Niger | 32.93% | 2018 | |
| 67 | Zimbabwe | 32.58% | 2018 | |
| 68 | Guatemala | 32.38% | 2018 | |
| 69 | Papua New Guinea | 32.37% | 2018 | |
| 70 | Japan | 32.32% | 2018 | |
| 71 | Tanzania | 31.79% | 2018 | |
| 72 | Kenya | 31.57% | 2018 | |
| 73 | Malaysia | 31.55% | 2018 | |
| 74 | Myanmar | 31.4% | 2018 | |
| 75 | Madagascar | 31.31% | 2018 | |
| 76 | Gambia | 31.29% | 2018 | |
| 77 | Somalia | 30.84% | 2018 | |
| 78 | Mali | 30.28% | 2018 | |
| 79 | Croatia | 29.44% | 2018 | |
| 80 | Uganda | 29.4% | 2018 | |
| 81 | Thailand | 29.29% | 2018 | |
| 82 | Tunisia | 28.73% | 2018 | |
| 83 | Lithuania | 28.39% | 2018 | |
| 84 | Nicaragua | 27.7% | 2018 | |
| 85 | Albania | 27.51% | 2018 | |
| 86 | Finland | 27.15% | 2018 | |
| 87 | Philippines | 26.95% | 2018 | |
| 88 | Laos | 26.89% | 2018 | |
| 89 | Belarus | 26.89% | 2018 | |
| 90 | Turkmenistan | 26.84% | 2018 | |
| 91 | Yemen | 26.62% | 2018 | |
| 92 | Ecuador | 26.59% | 2018 | |
| 93 | Colombia | 26.37% | 2018 | |
| 94 | Denmark | 25.93% | 2018 | |
| 95 | Cameroon | 25.72% | 2018 | |
| 96 | Syria | 25.33% | 2018 | |
| 97 | Hungary | 25.24% | 2018 | |
| 98 | Iraq | 25.15% | 2018 | |
| 99 | Qatar | 25.14% | 2018 | |
| 100 | Honduras | 24.9% | 2018 | |
| 101 | Cuba | 24.46% | 2018 | |
| 102 | Saudi Arabia | 24.44% | 2018 | |
| 103 | Bulgaria | 24.15% | 2018 | |
| 104 | Nepal | 23.98% | 2018 | |
| 105 | El Salvador | 23.93% | 2018 | |
| 106 | Turkey | 23.85% | 2018 | |
| 107 | Vietnam | 23.74% | 2018 | |
| 108 | South Korea | 23.69% | 2018 | |
| 109 | Norway | 23.16% | 2018 | |
| 110 | Bolivia | 23.02% | 2018 | |
| 111 | Jordan | 22.79% | 2018 | |
| 112 | Australia | 22.29% | 2018 | |
| 113 | Switzerland | 21.81% | 2018 | |
| 114 | Libya | 21.64% | 2018 | |
| 115 | Bosnia and Herzegovina | 21.36% | 2018 | |
| 116 | Mexico | 21.34% | 2018 | |
| 117 | France | 20.23% | 2018 | |
| 118 | Canada | 20.16% | 2018 | |
| 119 | Pakistan | 19.79% | 2018 | |
| 120 | Ethiopia | 19.4% | 2018 | |
| 121 | North Korea | 19.21% | 2018 | |
| 122 | Ghana | 18.37% | 2018 | |
| 123 | Belgium | 18.31% | 2018 | |
| 124 | Sweden | 17.78% | 2018 | |
| 125 | Kazakhstan | 17.43% | 2018 | |
| 126 | Romania | 17.32% | 2018 | |
| 127 | Spain | 17.31% | 2018 | |
| 128 | South Sudan | 17.14% | 2018 | |
| 129 | Benin | 17.07% | 2018 | |
| 130 | Czech Republic | 16.47% | 2018 | |
| 131 | Morocco | 16.37% | 2018 | |
| 132 | United Kingdom | 16.31% | 2018 | |
| 133 | Mozambique | 15.41% | 2018 | |
| 134 | Sri Lanka | 14.98% | 2018 | |
| 135 | Uzbekistan | 14.81% | 2018 | |
| 136 | Slovakia | 14.69% | 2018 | |
| 137 | Iran | 14.52% | 2018 | |
| 138 | South Africa | 14.31% | 2018 | |
| 139 | Nigeria | 13.65% | 2018 | |
| 140 | Brazil | 11.94% | 2018 | |
| 141 | Russia | 11.54% | 2018 | |
| 142 | Venezuela | 11.52% | 2018 | |
| 143 | Italy | 9.89% | 2018 | |
| 144 | Ukraine | 9.55% | 2018 | |
| 145 | Algeria | 8.78% | 2018 | |
| 146 | Poland | 7.75% | 2018 | |
| 147 | Netherlands | 7.18% | 2018 | |
| 148 | Indonesia | 7.1% | 2018 | |
| 149 | United States | 6.99% | 2018 | |
| 150 | India | 6.19% | 2018 | |
| 151 | Germany | 5.54% | 2018 | |
| 152 | China | 3.11% | 2018 |